Bread gets Hamotzi, the most important bracha. It usually covers whatever else is eaten during the meal.
After eating: Birkat Hamazon (Grace after Meals), after eating a kezayit of bread.
בָּרוּךְ אַתָּה ה׳ אֱלֹקֵינוּ מֶלֶךְ הָעוֹלָם, הַמּוֹצִיא לֶחֶם מִן הָאָרֶץ
Baruch atah Hashem, Elokeinu melech ha'olam, hamotzi lechem min ha'aretz.
Blessed are You, Hashem our God, King of the universe, who brings forth bread from the earth.
Bread gets Hamotzi, the most important bracha. It usually covers whatever else is eaten during the meal.
After eating: Birkat Hamazon (Grace after Meals), after eating a kezayit of bread.
This follows the common ruling of most poskim. For different customs or a specific question, ask a rabbi.